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Di-tert-butyltin(IV)–hydroxide–iodide, tBu2Sn(OH)I, the last missing member in the series of pure di-tert-butyltin(IV)–hydroxide–halides

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https://doi.org/10.48693/270
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dc.creatorReuter, Hans-
dc.date.accessioned2023-03-07T12:38:55Z-
dc.date.available2023-03-07T12:38:55Z-
dc.date.issued2022-05-20-
dc.identifier.citationReuter, H. (2022): Di-tert-butyltin(IV)-hydroxide-iodide, tBu2Sn(OH)I, the last missing member in the series of pure di-tert-butyltin(IV)-hydroxide-halides. Acta Crystallographica Section E, 78(6), 633-637.ger
dc.identifier.urihttps://doi.org/10.48693/270-
dc.identifier.urihttps://osnadocs.ub.uni-osnabrueck.de/handle/ds-202303078455-
dc.description.abstractThe crystal structure of di-tert-butyl­hydroxido­iodido­tin(IV), [Sn(C4H9)2I(OH)] or tBu2Sn(OH)I, consists of dimeric, centrosymmetric mol­ecules exhibiting the typical structural features of diorganotin(IV)-hydroxide-halides, R2Sn(OH)Hal. Two trigonal–bipyramidally coordinated tin(IV) atoms are bridged via two hydroxyl groups, resulting in a planar, four-membered {Sn—O}2 ring of rhombic shape, with acute angles at tin, obtuse angles at oxygen and two different Sn—O distances depending whether the oxygen atom adopts an axial or equatorial position at the tin(IV) atom. In contrast to its fluorine, chlorine and bromine homologues, no hydrogen bonds between the OH group and the halide atom exist, confining the inter­molecular inter­actions to van der Waals forces.eng
dc.relationhttps://doi.org/10.1107/S205698902200514Xger
dc.rightsAttribution 4.0 International*
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/*
dc.subjectcrystal structureeng
dc.subjecthydrolysiseng
dc.subjecttrigonal-bipyramidal coordinationeng
dc.subjectvan-der-Waals inter­actioneng
dc.subject.ddc540 - Chemieger
dc.titleDi-tert-butyltin(IV)–hydroxide–iodide, tBu2Sn(OH)I, the last missing member in the series of pure di-tert-butyltin(IV)–hydroxide–halideseng
dc.typeEinzelbeitrag in einer wissenschaftlichen Zeitschrift [Article]ger
orcid.creatorhttps://orcid.org/0000-0002-1251-0783-
dc.identifier.doi10.1107/S205698902200514X-
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